Q - If an employer believes a new hire is an alien, can s/he ask the person to produce a Green Card when filing out the I-9 Form?
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A - NO.  As the I-9 From (rev. 11-21-91) states, "Employers  CANNOT specify which document(s) they will accept from an employee."  This statement is repeated in the instructions accompanying the I-9 Form (OMB No. 1115-0136).  You can download a copy of the I-9 Form by going to the USCIS website I-9 download page.